Sextet transitions in Fe II
نویسندگان
چکیده
منابع مشابه
Diiron bridged-thiolate complexes that bind N2 at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox states.
All known nitrogenase cofactors are rich in both sulfur and iron and are presumed capable of binding and reducing N2. Nonetheless, synthetic examples of transition metal model complexes that bind N2 and also feature sulfur donor ligands remain scarce. We report herein an unusual series of low-valent diiron complexes featuring thiolate and dinitrogen ligands. A new binucleating ligand scaffold i...
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ژورنال
عنوان ژورنال: Monthly Notices of the Royal Astronomical Society
سال: 2001
ISSN: 0035-8711,1365-2966
DOI: 10.1046/j.1365-8711.2001.03996.x